Reaction kinetics of cluster impurities

Reaction kinetics of cluster impurities.

dimension di, while the rest of the d-dimensional space is occupied by identical mobile particles. The Smoluchowski rate theory suggests that the immobile reactants concentration, s(t), exhibits interesting behavior as a function of the codimension, d̄ ≡ d− di. This survival probability undergoes a survival-to-extinction transition at d̄c = 2. For d̄ < d̄c, a finite fraction of the immobile reactan...

The Gas Phase Oxidation of Acetaldehyde Reaction Mechanism and Kinetics

The mechanism of the low temperature oxidation of gaseous acetaldehyde was investigated in the temperature range of 1 50-400?°C. The minor, intermediate and major products were identified and measured quantitatively by sampling directly into the ionization chamber of an MS10-C2 mass spectrometer from the reactor. The formation of H2O, CO, CO2, HCOOH, H2, HCHO, CH3COOH and CH3OH as the major pro...

Cluster Kinetics of Granular Mixing

Granular mixing of identical particles that cluster together is a challenging and important engineering problem. Mixing requires the breakup of clusters, both by individual particle detachment and cluster fragmentation. We apply a population balance (distribution kinetics) approach to describe such size-distributed cluster processes. Expressions for mixing effectiveness and segregation measures...

Diffusion-Controlled Reaction Kinetics

3 Reaction Kinetics

Determination of the Rate Expression and Prediction of Reaction Progress for Irreversible Reactions 12 Integral Methods: Rates Dependent on a Single Constituent 12 Integral Methods: Rates Dependent on a Multiple Constituents 24 Differential Methods 30 Characteristic Reaction Times 32 Analysis of Multiple Simultaneous Reactions 36 Reversible Reactions 36 Reversibility of Reactions and its Relati...